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分散劑對ITO前驅物漿料穩(wěn)定性的影響
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國家“863”基金資助項目(2004AA303542)


Effect of Dispersants on Stability of ITO Precursor Slurry
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    摘要:

    以金屬銦和結晶四氯化錫為原料,通過加入各種添加劑制備了穩(wěn)定的ITO前驅物漿料。利用沉降實驗、Zeta電位、透射電鏡研究了分散劑對漿料穩(wěn)定性的影響。通過考察不同pH值條件下,分散劑的種類及用量對ITO漿料穩(wěn)定性的作用,探究其分散機理。結果表明,在ITO前驅物漿料中加入離子型分散劑乙醇胺,通過乙酸調節(jié)pH值,可使顆粒間具有較高靜電效應,在此基礎上加入高分子表面活性劑(PEG、PVP),使得顆粒間又具有空間位阻效應。從而防止了顆粒間的團聚,可得到高度分散的漿料。前驅物漿料顆粒粒度主要分布在10~20 nm之間。

    Abstract:

    The stable precursor slurry of indium-tin-oxide (ITO) was prepared using metal In and crystalloid tin tetrachloride as raw materials by adding different additives. The effect of dispersants on the stability of ITO precursor slurry was studied by Zeta potential value, TEM and sediment. The influences of pH value and dispersant content on stability of the slurry were investigated. And the effects of the different dispersant and their dispersing mechanism on the stability of the slurry were also investigated. The results show that a higher electrostatic effect could be obtained by adjusting pH value of medium and adding ionic dispersant. Based on the above mentioned, non-ionic surfactants (PEG, PVP) were added, resulting in creating a steric hindered effect among particles, which prevented the agglomeration of the particles so as to obtain a high dispersed and steady slurry. The particle sizes of the slurry were about 10~20 nm. The following finding can be drawn from the experiment that the optimum contents of dispersants are PEG 10% and monoethanolamine 2.5% (mass fraction).

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張 楠,劉家祥,吳 妲.分散劑對ITO前驅物漿料穩(wěn)定性的影響[J].稀有金屬材料與工程,2009,38(6):1033~1037.[Zhang Nan, Liu Jiaxiang, Wu Da. Effect of Dispersants on Stability of ITO Precursor Slurry[J]. Rare Metal Materials and Engineering,2009,38(6):1033~1037.]
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  • 收稿日期:2008-07-01
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