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熔體冷速對Co48Cr15Mo14C15B6Er2塊體非晶合金晶化及磁性能的影響
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甘肅省教育廳開放基金(0503-08);蘭州理工大學(xué)優(yōu)秀中青年基金(Q200303)項目資助


Effect of Melt Cooling Rate on Crystallization and Magnetic Properties of Co48Cr15Mo14C15B6Er2 Bulk Metallic Glass
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    摘要:

    分別用單輥甩帶法和銅模鑄造法制備了Co48Cr15Mo14C15B6Er2非晶合金薄帶以及Φ2 mm和Φ7 mm的非晶圓棒。利用差熱分析儀和振動樣品磁強計研究了冷卻速率對Co48Cr15Mo14C15B6Er2非晶合金的晶化動力學(xué)及磁性能的影響。結(jié)果發(fā)現(xiàn),冷卻速率對晶化動力學(xué)有顯著影響。對非等溫晶化來說,隨著冷速降低,試樣的玻璃轉(zhuǎn)變溫度下降,玻璃轉(zhuǎn)變激活能減小。雖然晶化峰值溫度不受冷速的影響,但是晶化激活能隨冷速降低而降低。對等溫晶化來說,雖然不同冷速條件下制備的試樣都表現(xiàn)出擴散控制的晶核三維長大過程,但

    Abstract:

    The Co48Cr15Mo14C15B6Er2 amorphous ribbon and rods with diameters of 2mm and 7mm were prepared by melt spinning and copper mold casting. The different Scanning calorimetry and the vibrating sample magnetometer were employed to investigate the effect of cooling rate on crystallization kinetics and magnetic properties of metallic Co48Cr15Mo14C15B6Er2 glass. It was found that the cooling rate had significant influence on the crystallization kinetics. In the case of non-isothermal crystallization process, the glass transition temperature and the activation energy for the glass transition decreased with decreasing of cooling rate. The activation energy for crystallization also decreased with decreasing of cooling rate, in despite of that the peak temperature of crystallization was independent of cooling rate. Although the isothermal crystallization was governed by diffusion-controlled three-dimensional growth with decreasing of nucleation rate for Co48Cr15Mo14C15B6Er2 glasses under different cooling rates, how rapidly the nucleation rate decreased was related to cooling rate. The more rapid the cooling rate was, the faster the decrease of the rate was. The magnetic properties of Co48Cr15Mo14C15B6Er2 glass was significantly affected by cooling rate. The sample obtained at high cooling rate took on paramagnetic property, whereas the sample obtained at low cooling rate took on ferromagnetic property. The saturation magnetization increased with decreasing of cooling rate.

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袁子洲,姚 林,包石磊,王英君.熔體冷速對Co48Cr15Mo14C15B6Er2塊體非晶合金晶化及磁性能的影響[J].稀有金屬材料與工程,2009,38(6):999~1004.[Yuan Zizhou, Yao Lin, Bao Shilei, Wang Yingjun. Effect of Melt Cooling Rate on Crystallization and Magnetic Properties of Co48Cr15Mo14C15B6Er2 Bulk Metallic Glass[J]. Rare Metal Materials and Engineering,2009,38(6):999~1004.]
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  • 收稿日期:2009-02-25
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