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CeO2對牙科云母玻璃陶瓷微觀結(jié)構(gòu)和性能的影響
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國家自然科學(xué)基金資助項(xiàng)目(50672127)


Effect of CeO2 Addition on the Property of Dental Mica Based Glass-Ceramic
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    摘要:

    針對添加大劑量氧化物是否會對云母玻璃陶瓷的性能產(chǎn)生不利影響的這一關(guān)鍵性問題,運(yùn)用DTA、XRD、SEM和機(jī)械性能測試等方法研究了添加不同的CeO2(作為著色劑),對氟金云母玻璃陶瓷微觀結(jié)構(gòu)、力學(xué)性能和可切削性能的影響。結(jié)果表明:添加2%~5%(質(zhì)量分?jǐn)?shù), 下同)CeO2后,牙科氟金云母玻璃陶晶體主晶相無明顯改變,晶體直徑明顯變大。隨著CeO2含量的增加,三點(diǎn)彎曲強(qiáng)度先增加后降低,切削性能逐漸改善。在氟金云母玻璃陶瓷中添加3%以下的CeO2對材料的力學(xué)性能的提高有促進(jìn)作用; 添加量過高時(shí), 雖切削性能有所提

    Abstract:

    To evaluate the effect of CeO2 on the microstructure and property of SiO2-Al2O3-MgO-Na2O-K2O-F system, 2wt%, 3wt%, 4wt%, 5wt% CeO2 were added respectively. Crystallization behaviors, crystalline phases, microstructures of the glass-ceramics with various compositions were investigated by differential thermal analysis (DTA), X-ray diffraction (XRD) and scanning electron micro scope (SEM) analysis. Three-point bending strength, micro hardness, machinability and wear abrationlosing weight were also measured. The results revealed that the main crystalline phase of glass ceramics wasn’t changed, but the aspect ratio of mica crystals increased upon adding CeO2 With increasing of the CeO2 content, the three-point bending strength firstly increased and then decreased, microhardness firstly decreased and then increased, wear resistance decreased and machinability increased obviously. The addition of 3% CeO2 enhanced bending strength of SiO2-Al2O3-MgO-Na2O-K2O-F glass-ceramics at the same time could give appropriate color similar to teeth. The excessive addition would be unbeneficial to improving of bending strength and wear resistance

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孫 翔,陳吉華,李光新,馬新沛,金志浩. CeO2對牙科云母玻璃陶瓷微觀結(jié)構(gòu)和性能的影響[J].稀有金屬材料與工程,2009,38(5):862~865.[Sun Xiang, Chen Jihua, Li Guangxin, Ma Xinpei, Jin Zhihao. Effect of CeO2 Addition on the Property of Dental Mica Based Glass-Ceramic[J]. Rare Metal Materials and Engineering,2009,38(5):862~865.]
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  • 收稿日期:2008-05-20
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