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磁熱處理對La-Mg-Ni-Cu合金相結構與電化學性能的影響
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上海市科委西部開發(fā)科技合作項目(065258036);上海市青年科技啟明星計劃(06QA14021)及全國博士學位論文作者專項資助項目(200746)


Influence of Magnetic-Heat Treatment on Phase Structure and Electrochemical Properties of La-Mg-Ni-Cu Alloys
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    摘要:

    考察了La0.67Mg0.33Ni2.5Cu0.5合金分別在鑄態(tài)、熱處理后及磁熱處理后3種狀態(tài)下的相結構及其電化學性能。并通過XRD分析合金物相組成及SEM觀察合金組織形貌,研究了Cu部分取代Ni以及有無外加磁場下熱處理對合金相結構與電化學性能的作用規(guī)律。結果表明,La0.67Mg0.33Ni2.5Cu0.5鑄態(tài)合金經過50次循環(huán)后,放電容量保持率從64.40%提高到72.44%;經磁熱處理的La0.67Mg0.33Ni2.5Cu0.5合金最大放電容量為328.2 mAh/g,較常規(guī)熱處理合金的容量提高了

    Abstract:

    The phase structure and electrochemical properties of La0.67Mg0.33Ni2.5Cu0.5 alloys as cast and treated by heat treatment and magnetic-heat treatment were studied in this paper. The influence of the heat treatment and magnetic-heat treatment as well as Ni substituted partly with Cu on the phase structure and electrochemical properties of La-Mg-Ni-Cu alloys were investigated by XRD and SEM analysis. The results show that the retention of discharge capacity of as-cast La0.67Mg0.33Ni2.5Cu0.5 alloy is increased to 72.44% from 64.40% after 50 cycles. The maximum discharge capacity of La0.67Mg0.33Ni2.5Cu0.5 alloy after magnetic-heat treatment is 328.2mAh/g, which is 31.51% larger than that of La0.67Mg0.33Ni2.5Cu0.5 alloy after heat treatment. Its retention of discharge capacity is 75.89% after 50 cycles. The characteristic of discharge voltage platform is much flatter and longer, the limit current density is increased and the diffusion speed of hydrogen in the alloys increases.

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趙顯久,李 謙,劉 靜,周國治,林根文.磁熱處理對La-Mg-Ni-Cu合金相結構與電化學性能的影響[J].稀有金屬材料與工程,2009,38(5):857~861.[Zhao Xianjiu, Li Qian, Liu Jing, Zhou Guozhi, Lin Genwen. Influence of Magnetic-Heat Treatment on Phase Structure and Electrochemical Properties of La-Mg-Ni-Cu Alloys[J]. Rare Metal Materials and Engineering,2009,38(5):857~861.]
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  • 收稿日期:2008-05-20
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