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電解液組成對純鈦微弧氧化膜結(jié)構(gòu)及光催化活性的影響
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Effect of Electrolyte Composition on Structure and Photocatalytic Activity of Micro-Arc Oxidation Coating on Pure Titanium
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    摘要:

    分別在鎢酸鈉和磷酸二氫鉀電解液中制備了純鈦的微弧氧化(MAO)膜,利用SEM、EDX、XRD分析了膜層的形貌、元素分布及相組成,并測試了2種膜層的光催化活性。結(jié)果表明,純鈦在2種電解液中均形成粗糙多孔的微弧氧化膜層,但鎢酸鈉溶液中形成的膜層表面的孔洞尺寸較小、分布較均勻。膜層的元素組成和相組成與電解液成分有關(guān),鎢酸鈉溶液中的膜層由W、Ti、O元素組成,W在膜層中近似均勻分布,銳鈦礦與金紅石的含量比(質(zhì)量比)為27:73,而磷酸二氫鉀電解液中的膜層由P、Ti、O元素組成,P從表面向內(nèi)層逐漸增加,銳鈦礦與金紅

    Abstract:

    Micro-arc oxidation (MAO) films on pure titanium were prepared in sodium tungsten electrolyte and in potassium dihydrogen phosphate electrolyte, respectively. The surface and cross-section morphologies, the element distribution and the phase composition of coatings were analyzed by means of SEM, EDX, XRD. The photocatalytic activity of the two coatings was tested by UV-Vis spectra. The results show that MAO coatings prepared in the two electrolytes are rough and micro-porous, but the pores on the surface of the coating prepared in the sodium tungsten electrolyte are smaller and more homogeneous. The composition and the phase constitution of the coatings depent on the electrolyte composition, The coating prepared in the sodium tungstate solution mainly consists of elements W, Ti, O, element W is distributed homogeneously in the coating, and the ratio of anatase to rutile is 27:73, while the elements of the coating prepared in the potassium dihydrogen phosphate electrolyte are P, Ti, O, the content of P gradually increased from the surface to the dense layer, and the ratio of anatase to rutile is 84:16. The result of absorbance test shows that the photocatalytic activity of the coating formed in sodium tungsten electrolyte is higher than that of the coating formed in the potassium dihydrogen phosphate electrolyte, because of its larger specific surface area

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何 劍,蔡啟舟,駱海賀,魏伯康,李定駿.電解液組成對純鈦微弧氧化膜結(jié)構(gòu)及光催化活性的影響[J].稀有金屬材料與工程,2009,38(5):794~798.[He Jian, Cai Qizhou, Luo Haihe, Wei Bokang, Li Dingjun. Effect of Electrolyte Composition on Structure and Photocatalytic Activity of Micro-Arc Oxidation Coating on Pure Titanium[J]. Rare Metal Materials and Engineering,2009,38(5):794~798.]
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  • 收稿日期:2008-05-19
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