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形變溫度對FeMnSiCrNiC合金第二相方向性析出及記憶效應的影響
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國家自然科學基金(50501015)和中國博士后科學基金(20080430670)


Effects of Deformation Temperature on the Directional Precipitation of Second Phase and SME in an FeMnSiCrNiC Alloy
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    摘要:

    基于控制第二相方向性析出提高鐵基合金形狀記憶效應的構(gòu)想,研究了不同形變溫度對Fe13.53Mn4.86Si8.16Cr3.82Ni0.16C合金g/e界面(母相g與誘發(fā)馬氏體e之間界面)的數(shù)量和結(jié)構(gòu)及隨后時效第二相析出的數(shù)量和方向性的影響,以及第二相析出的數(shù)量和方向性對馬氏體相變和形狀記憶效應的影響。掃描電鏡分析顯示,形變溫度遠高于Ms時,無g /e界面產(chǎn)生,時效后第二相析出少;形變溫度接近Ms時,產(chǎn)生大量g /e界面,時效后析出第二相數(shù)量很多,且方向性良好;形變溫度進一步接近Ms時,g /e界面交叉,導致時效后方向性的第二相也交叉。透射電鏡分析顯示,析出方向性Cr23C6第二相的合金再次進行預變形時,產(chǎn)生的應力誘發(fā)馬氏體具有單一方向。原因在于方向性Cr23C6及其產(chǎn)生的應力場對馬氏體相變產(chǎn)生約束作用,避免馬氏體片之間的交叉,使其具有更好的可逆轉(zhuǎn)變性。

    Abstract:

    Based on the principle that the aligned precipitation of second phase can improve shape memory effect (SME), the following effects were investigated, including the effects of different deformation temperatures on the amount and the structure of g /e interface, on the amount and orientation of the second precipitation phase after subsequent aging, and the effects of whick on the martensite transformation and SME. The SEM analysis shows that no g /e interfaces were produced after deformation at the temperature far higher than Ms , and few carbides precipitated after ageing. Much more g /e interfaces were produced after deformation at temperature near Ms , and much more directional carbides precipitated after ageing. With further decreasing the deformation temperature to Ms, some g /e interfaces intersected and carbides precipitated along different directions after ageing. TEM analysis shows that the thick stress-induced martensite plates had the uniform orientation in the 5% preformed alloys with orientationaly precipitated carbides. The reason is that Cr23C6 and strain fields produced by Cr23C6 will restrain martensite transformation and avoid the intersection among martensite plates thus remarkably improve the reversibility of stress-induced martensite.

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張 偉,李 寧,文玉華,謝文玲,王杉華.形變溫度對FeMnSiCrNiC合金第二相方向性析出及記憶效應的影響[J].稀有金屬材料與工程,2009,38(4):681~685.[Zhang Wei, Li Ning, Wen Yuhua, Xie Wenling, Wang Shanhua. Effects of Deformation Temperature on the Directional Precipitation of Second Phase and SME in an FeMnSiCrNiC Alloy[J]. Rare Metal Materials and Engineering,2009,38(4):681~685.]
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  • 收稿日期:2008-03-28
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