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C/C復(fù)合材料表面TaC涂層的制備和生成機(jī)制
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國家重點基礎(chǔ)研究發(fā)展規(guī)劃(“973”計劃)項目(2006CB600908)


Preparation and Formation Mechanism of TaC Coating on Carbon/Carbon Composites
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    摘要:

    報道了一種在C/C復(fù)合材料基體上制備抗燒蝕TaC涂層的新方法。采用紅外光譜、XRD及SEM表征了生成TaC涂層的Ta源:TaO2F·rH2O·TaF5。采用SEM觀察了不同溫度下轉(zhuǎn)變生成的TaC涂層的形貌。在1200 ℃高溫?zé)崽幚?,TaC涂層形貌為細(xì)顆粒狀,在1800 ℃高溫?zé)崽幚砗?,TaC涂層為柱狀晶。TaC的生成機(jī)制為:TaO2F·rH2O·TaF5高溫分解凝聚生成的Ta2O5沉積在C/C復(fù)合材料基體表面,碳原子在Ta2O5中擴(kuò)散反應(yīng)生成TaC,TaC涂層形貌可由生成Ta2O5的凝聚成核理論解釋

    Abstract:

    A new technology for preparation of TaC coating on Carbon/carbon composites is reported. TaC was turned from TaO2F·rH2O·TaF5, which was characterized by FITR, XRD and SEM. The morphologies of TaC coating at different temperatures were observed by SEM. At 1200 ℃, the TaC coating shows the particular form. When the heat treatment temperature increased to 1800 ℃, the TaC coating was mainly columnar. The formation mechanism of TaC is that Carbon atom diffuse into Ta2O5 deposit, which is coming from TaO2F·rH2O·TaF5 and reacted into TaC at high temperature. The morphology of TaC coating can be interpreted by the theory of Ta2O5 deposited nucleation

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李江鴻,張紅波,熊 翔,肖 鵬,黃伯云. C/C復(fù)合材料表面TaC涂層的制備和生成機(jī)制[J].稀有金屬材料與工程,2009,38(3):496~499.[Li Jianghong, Zhang Hongbo, Xiong Xiang, Xiao Peng, Huang Baiyun. Preparation and Formation Mechanism of TaC Coating on Carbon/Carbon Composites[J]. Rare Metal Materials and Engineering,2009,38(3):496~499.]
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  • 收稿日期:2008-02-19
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