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Ni-Fe-Ga-Co磁性記憶合金微觀組織與力學(xué)行為
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國(guó)家自然科學(xué)基金項(xiàng)目(50131010)


Microstructure and Mechanical Properties of Ni-Fe-Ga-Co Ferromagnetic Shape Memory Alloys
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    摘要:

    系統(tǒng)研究Ni-Fe-Ga-Co磁性形狀記憶合金的顯微組織結(jié)構(gòu)以及力學(xué)行為,闡明摻Co對(duì)NiFeGa合金中γ相析出的影響規(guī)律,探明γ相增韌的微觀機(jī)制。結(jié)果表明,鑄態(tài)Ni-Fe-Ga-Co合金室溫組織由馬氏體和γ相兩相組成,γ相數(shù)量隨Co含量增加而增多。Fe和Co原子在馬氏體相中存在最大飽和濃度,當(dāng)二者含量之和超過16 at%時(shí),剩余的Fe和Co原子以γ相形式析出。γ相為富Fe和Co而貧Ga相,且Fe和Co原子的最大飽和濃度約為23 at%。合金的屈服強(qiáng)度和斷裂強(qiáng)度隨Co含量增多呈增大趨勢(shì)。斷口觀察發(fā)現(xiàn),基體相為解理斷裂,小尺寸的γ相被裂紋繞過或被整體拔出,大尺寸的γ相被拉長(zhǎng)、撕裂或整體拔出,說明γ相有利于改善合金韌性,但增韌效果受到γ相尺寸的影響

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    The microstructure and mechanical properties of Ni56Fe17Ga27-xCox(x=0, 2, 4, 6) magnetic shape memory alloys have been studied, and the influence of Co addition on γ phase and the mechanism for increasing toughness by γ phase were revealed. The results show that the microstructure of as-melted alloys is composed of martensite phase and γ phase at room temperature. With increasing Co content, the volume of γ phase increases. For the martensite phase, the saturation solubility of Fe and Co atoms is fixed. If the total content of Fe and Co atoms exceeds 16 at %, the residual atoms will exist in the form of γ phase, which is rich in Fe and Co atoms. Besides, the saturation solubility of Fe and Co atoms in γ phase is around 23 at %. The tensile tests show that the yielding strength and fracture strength increase with increasing Co content. The fracture mechanism of martensite phase is transcrystalline fracture, and the γ phase is gliding fracture, it proves that the γ phase improves the toughness of experimental alloys

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高智勇,隋解和,李 民,余彗茹,蔡 偉. Ni-Fe-Ga-Co磁性記憶合金微觀組織與力學(xué)行為[J].稀有金屬材料與工程,2009,38(2):323~326.[Gao Zhiyong, Sui Jiehe, Li Min, Yu Huiru, Cai Wei. Microstructure and Mechanical Properties of Ni-Fe-Ga-Co Ferromagnetic Shape Memory Alloys[J]. Rare Metal Materials and Engineering,2009,38(2):323~326.]
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  • 收稿日期:2008-01-24
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