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快速凝固法制備過飽和CuCr合金時效析出動力學(xué)
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國家自然科學(xué)基金(50361003);云南省自然科學(xué)基金重點項目(2006E003Z)及昆明理工大學(xué)創(chuàng)新基金 資助


Kinetics of Aging Precipitation of CuCr Alloy by Rapidly Solidification
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    摘要:

    在不同時效溫度下研究霧化法制備過飽和CuCr合金的時效析出動力學(xué)。通過能譜測定不同時刻的析出相體積分數(shù),用Avrami方程分析不同溫度的時效動力學(xué),發(fā)現(xiàn)擴散是相變的主要控制因素,而固溶原子、雜質(zhì)、空位、位錯、晶界和點陣畸變等都會對析出動力學(xué)產(chǎn)生影響。研究發(fā)現(xiàn),低溫時效的初期會形成無序的溶質(zhì)富集區(qū),析出相與基體之間保持共格關(guān)系。電子衍射和能譜分析表明,隨著時效時間的增加,Cr元素不斷在基體中富集,會形成明顯的G.P區(qū),最后形成單質(zhì)Cr相。而在高溫時效時,由于原子遷移的激活能容易滿足,Cr元素析出動力較大且富集很快,完成析出過程的時間很短,會在材料內(nèi)部迅速生成單質(zhì)Cr相,很難觀察到G.P區(qū)

    Abstract:

    Supersaturated CuCr solid solution was prepared by pulverization. After that, the aging dynamics were analyzed at different temperatures. The results showed that the G.P zone was presented at relatively low temperature. We could observe a coherent interface between precipitated phase and matrix. The results that were obtained both from transmission electron microscope (TEM) and Electron Energy Disperse Spectroscopy (EDS) revealed that as aging time increased, the amount of Cr metal phase also increased due to solute enrichment process. On the other hand, the activation energy for atomic diffusion was reduced at high temperature. As a result, the metal phases of Cr were formed very fast. The fractional volume of the precipitated phase was measured by EDS and then applied Avrami equation to analyze the dynamical effect of aging. Finally we concluded that the phase transition in CuCr alloy was determined by aging dynamics and diffusion was the most important effect of aging process, other factors such as solute species, impurities, vacancies, dislocations, grain boundaries and lattice distortions may be affected this process, too.

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馮 晶,陳敬超,于 杰,肖 冰,李 強,周曉龍.快速凝固法制備過飽和CuCr合金時效析出動力學(xué)[J].稀有金屬材料與工程,2009,38(2):281~285.[Feng Jing, Chen Jingchao, Yu Jie, Xiao Bing.,Li Qiang, Zhou Xiaolong. Kinetics of Aging Precipitation of CuCr Alloy by Rapidly Solidification[J]. Rare Metal Materials and Engineering,2009,38(2):281~285.]
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  • 收稿日期:2008-01-31
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