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熔鹽法Cf/SiC復(fù)合材料表面鈦金屬化研究
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Ti Metallization of Cf/SiC Composites Surface by Molten Salt Reaction
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    摘要:

    為了實(shí)現(xiàn)Cf/SiC復(fù)合材料與難熔金屬的連接,通過(guò)熔鹽法在Cf/SiC復(fù)合材料表面沉積鈦金屬層。用SEM和EDS研究金屬化層的形貌及成分;用X射線衍射分析金屬化層的相組織;用定量金相法測(cè)量釬焊料的鋪展特性。研究表明:鈦金屬化層均勻致密,與基體結(jié)合緊密,鈦金屬可滲入纖維間孔隙,比較完整地包覆在Cf/SiC復(fù)合材料外表面。金屬化層主要成分為T(mén)iC、Ti5Si3。金屬化層與SiC界面分為3層,由內(nèi)到外主要成分為T(mén)i5Si3、TiC和Ti5Si3。表面金屬化后的Cf/SiC復(fù)合材料與鈦合金釬焊料潤(rùn)濕性明顯改善,潤(rùn)濕角從153.9o降低為13.2o

    Abstract:

    Ti metallized coating was prepared on the surface of carbon fiber reinforced silicon carbide matrix (Cf/SiC) composite by molten salt reaction to make joining the composite with high melt point metals such as Ti. The morphologies and compositions of Ti metallized coating were analyzed by SEM and EDS. The phase components were assessed by XRD. The wettability of the solder was measured by quantitative metallography. The results show that Ti metallized coating is uniform and dense, and bound with the matrix closely. Ti can infiltrate into the gaps of the fibers, and cover the surfaces of the Cf/SiC composite. The main phases of the metalized coating consist of TiC and Ti5Si3. There are three transition layers between SiC and the metallized, i. e. Ti5Si3 layer, TiC layer and Ti5Si3 layer. The wettability of Cf/SiC composites surface to Ti is greatly improved by metallization, and the contact angle is deceased from 153.9° to 13.2° at 950 oC

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周文淵,鄭曉慧,堵永國(guó),張為軍,蘆玉峰.熔鹽法Cf/SiC復(fù)合材料表面鈦金屬化研究[J].稀有金屬材料與工程,2009,38(2):209~213.[Zhou Wenyuan, Zheng Xiaohui, Du Yongguo, Zhang Weijun, Lu Yufeng. Ti Metallization of Cf/SiC Composites Surface by Molten Salt Reaction[J]. Rare Metal Materials and Engineering,2009,38(2):209~213.]
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  • 收稿日期:2008-09-11
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