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Ru-Mn-AC多元復(fù)合電極材料的電化學(xué)性能
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Electrochemical Property of Ru-Mn-AC Multi-Element Composite Electrode Materials
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Supported by National Natural Science Foundation of China (50577075)

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    摘要:

    以提高超級(jí)電容器電極材料的電化學(xué)性能為目的,在活性碳粉末中摻入二氧化釕和二氧化錳,作為電極材料的活性物質(zhì),從而制備氧化物/活性炭多元復(fù)合電極,組裝成超級(jí)電容器單元。經(jīng)循環(huán)伏安、恒流充放電和交流阻抗測(cè)試的結(jié)果表明:在活性碳粉末中摻入20%的二氧化錳時(shí),復(fù)合電極的比容量為128 F/g,阻抗為2.62 Ω;在活性碳粉末中摻入二氧化釕和二氧化錳各20%時(shí),多元復(fù)合電極的比容量為266 F/g,阻抗為0.86 Ω,經(jīng)1500次循環(huán)充放電后,電容量幾乎無(wú)衰減,得出由活性炭、二氧化釕和二氧化錳構(gòu)成的多元復(fù)合電極是一種理想的超級(jí)電容器電極材料。

    Abstract:

    In order to improve the performances of electrode materials for super-capacitors, multi-element composite electrodes were prepared using RuO2 and MnO2 as active materials,and active carbon as basic materials. Good electrochemical performances of the composite electrodes were confirmed by cyclic voltammetry, galvano static charge/discharge and ac impedance measurements. When the content of MnO2 is 20wt% in composite electrode materials, the specific capacitance of MnO2/AC composite electrodes can reach 128 F/g with a resistance of 2.62 Ω. When the contents of RuO2 and MnO2 are separately 20wt% in composite electrode materials, the specific capacitance of RuO2/MnO2/AC composite electrodes can reach 266 F/g with a resistance of 0.86 Ω almost without any change of capacitance during 1500 cycles of charge/discharge. It is indicated that the multi-factor composite electrodes with RuO2/ MnO2 / AC are ideal electrode materials for super-capacitors.

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張 莉,宋金巖,鄒積巖. Ru-Mn-AC多元復(fù)合電極材料的電化學(xué)性能[J].稀有金屬材料與工程,2009,38(1):11~14.[Zhang Li, Song Jinyan, Zou Jiyan. Electrochemical Property of Ru-Mn-AC Multi-Element Composite Electrode Materials[J]. Rare Metal Materials and Engineering,2009,38(1):11~14.]
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  • 收稿日期:2008-08-20
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