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鎂合金在大氣環(huán)境中電偶腐蝕行為及規(guī)律的研究
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TG146.4

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Supported by National Natural Science Foundation of China (59971011 and 50499331-8), Project of Science and Technology Ministry of China (2004DKA 10080)


Research on Atmospheric Galvanic Corrosion Evaluation of Magnesium Alloy
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    摘要:

    在北京大氣環(huán)境下,研究AM60鎂合金和不同金屬材料(碳鋼、不銹鋼、黃銅和鋁合金)偶接的電偶腐蝕行為規(guī)律。研究表明,鎂合金作為陽(yáng)極發(fā)生不同程度的電偶腐蝕,通過1a的北京大氣環(huán)境下的暴露試驗(yàn)后,AM60鎂合金的電偶腐蝕效應(yīng)由強(qiáng)到弱的順序?yàn)椋禾间?、黃銅、不銹鋼和鋁合金,其中鎂合金與LY12鋁合金偶接的電偶腐蝕效應(yīng)最小。通過與其它地區(qū)室外暴曬的鎂合金電偶腐蝕效應(yīng)的對(duì)比,表明環(huán)境因素影響著鎂合金的電偶腐蝕效應(yīng)。同時(shí)陰極材料、試驗(yàn)時(shí)間、試樣尺寸(偶接面積)和試驗(yàn)環(huán)境都會(huì)對(duì)鎂合金電偶腐蝕效應(yīng)產(chǎn)生影響。經(jīng)1a曝曬的AM60鎂合金形成了具有保護(hù)性的腐蝕產(chǎn)物層阻礙了腐蝕發(fā)展。北京地區(qū)高自然降塵量導(dǎo)致金屬表面濕潤(rùn)時(shí)間加大,從而加速了AM60鎂合金的電偶腐蝕。采用XRD方法分析表面的腐蝕產(chǎn)物,用金相顯微鏡和掃描電鏡(SEM)觀察試樣腐蝕后的表面形貌特征和腐蝕產(chǎn)物的結(jié)構(gòu),并用與之相連的能譜儀分析腐蝕產(chǎn)物中的元素組成。

    Abstract:

    This paper presents the galvanic corrosion behaviors of AM60 magnesium alloy coupled with variable materials(carbon steel,stainless steel,brass and aluminum alloy) in the outdoor atmosphere of Beijing.The correlations among mass variation,galvanic effect and atmospheric factors for AM60 magnesium alloy coupons were investigated.Surface morphologies were observed by scanning electron microscopy(SEM),and X-ray diffraction(XRD) was used to analyze the crystal corrosion products.The results showed that the AM60 magnesium alloy acted as anodic material when it coupled with tested metals.The arrangement order of galvanic effect from strong to little is carbon steel,brass,stainless steel and aluminum alloy after 12 months exposure in Beijing atmosphere.The atmospheric galvanic effect of magnesium alloys coupled with aluminum alloy is the least among the tested coupled alloys during any testing periods because the effective potential difference of the cathode(AM60) and anode(aluminum alloy) is the least for all of tested coupled alloys.The atmospheric galvanic effects in Beijing compared with other cities indicate that atmospheric environment is most important factor.The atmospheric galvanic effects for magnesium alloys are affected by cathode alloy,testing time,sample acreage and environment condition.And no intact and protective corroded products layer was formed to prevent further corrosion after 1 year exposure.The edge of AM60 coupon suffered harsh galvanic corrosion,which was limited by the existing of thin-film on the coupon surface.The high dust precipitation of Beijing could prolong the time of wetness on metal surface.So,the atmospheric corrosion of AM60 magnesium alloy coupled with different metals could be accelerated.

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肖葵 董超芳 李久青 李曉剛 魏丹.鎂合金在大氣環(huán)境中電偶腐蝕行為及規(guī)律的研究[J].稀有金屬材料與工程,2007,36(2):201~207.[Xiao Kui, Dong Chaofang, Li Jiuqing, Li Xiaogang, Wei Dan. Research on Atmospheric Galvanic Corrosion Evaluation of Magnesium Alloy[J]. Rare Metal Materials and Engineering,2007,36(2):201~207.]
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  • 最后修改日期:2005-11-23
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