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燒結(jié)工藝對納米AgSnO2復(fù)合材料致密度的影響
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TM934.14

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科技部“中小企業(yè)創(chuàng)新基金”(02C26213310205)資助


Influence of Sintering Processes on the Density of Nano-AgSnO2 Composites
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    摘要:

    對化學(xué)鍍法制備的納米AgSnO2粉末分別采用常壓、熱壓和真空燒結(jié)的方法制成AgSnO2復(fù)合材料,研究了燒結(jié)方法及工藝對致密度的影響。結(jié)果表明,采用常壓燒結(jié),雖然成型壓力、燒結(jié)溫度和時(shí)間對致密度有一定的影響,但復(fù)壓、復(fù)燒后,材料的致密度十分接近。熱壓能在短時(shí)間內(nèi)獲得96%以上的致密度,但復(fù)燒時(shí)膨脹嚴(yán)重,甚至出現(xiàn)鼓泡。真空燒結(jié)對去除吸附物有利,但仍會有少量殘留并導(dǎo)致復(fù)燒時(shí)出現(xiàn)膨脹。在較低的壓力下成型并采用分段保溫?zé)Y(jié),不但能消除吸附物的影響,復(fù)燒后還可以得到94%的致密度。研究表明,納米粉末表面大量的吸附物以及由此造成的封閉在壓坯中的氣體是阻礙燒結(jié)致密化的根本原因。

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    The influence of sintering process on the density of nano-AgSnO2 composite was investigated using AgSnO2 powder prepared by electroless plating, adopting air sintering, hot pressing and vacuum sintering. The results show that density changed with compacting pressure, sintering temperature and sintering time when sintered in air, while the final density was close after repressing and resintering. For hot pressing, a density with higher than 96% could be achieved in a short time, but serious expansion and blistering ocurred. Vacuum sintering could help to wipe off adsorbates, but some residual still remained in the compact, and the expansion occurred during resintering. Low pressure compaction and step isothermal sintering could remove most of the adsorbates, and a high density of 94% was obtained after resintering. The large amount of absorbates on nano-AgSnO2 powder surface which led gases closed in the compact during sintering were found to be the main causes that affected densification process .

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王尚軍 凌國平 孟亮.燒結(jié)工藝對納米AgSnO2復(fù)合材料致密度的影響[J].稀有金屬材料與工程,2007,36(1):157~161.[Wang Shangjun, Ling Guoping, Meng Liang. Influence of Sintering Processes on the Density of Nano-AgSnO2 Composites[J]. Rare Metal Materials and Engineering,2007,36(1):157~161.]
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  • 最后修改日期:2006-05-18
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