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Mg-Zn-Y三元合金中二十面體準(zhǔn)晶相生長(zhǎng)形貌及其演化
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TG113.12

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Growth Morphology and Evolution of Icosahedrai Quasicrystai in Mg-Zn-Y Ternary Alloys
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    摘要:

    采用常規(guī)凝固方法在Mg-Zn-Y三元合金系中獲得了大體積分?jǐn)?shù)的二十面體準(zhǔn)晶。二十面體準(zhǔn)晶相有2種典型形貌特征:一種為花瓣?duì)?,另一種為多邊形形狀。這是準(zhǔn)晶在生長(zhǎng)過程中形貌演化的結(jié)果。合金的成分和冷卻速率是影響準(zhǔn)晶形貌的主要崗素。準(zhǔn)晶合金中生成的低溫相越多,冷卻速率越慢,準(zhǔn)晶相生長(zhǎng)的時(shí)間和空間條件越好,準(zhǔn)晶相越容易由花瓣?duì)钛莼啥噙呅螤?。?zhǔn)晶的形成有包晶反應(yīng)參與,包晶反應(yīng)是一種由初生固態(tài)相擴(kuò)散控制的反應(yīng),因此,準(zhǔn)晶在生長(zhǎng)初期和最終形態(tài)其元素含量有明顯差別,分析表明,準(zhǔn)晶生長(zhǎng)初期Mg元素含量偏低,Zn和Y元素含量偏高。

    Abstract:

    A large volumetric fraction of icosahedral quasicrystal was gained through ordinary solidification technology in Mg-Zn-Y ternary alloys.The icosahedral quasicrystal in Mg-Zn-Y ternary alloys have two typical morphology features:petal-like,polygon-like.The different features of icosahedral quasicrystal are attributed to their morphology evolution.Alloying composition and cooling rate are major factors affecting the morphology of icosahedral quasicrystal.In the solidification process of quasicrystal alloys,the more the low-temperature phases and the less the cooling rate,the much more easily the changing into the polygon-like morphology from petal-like one takes place.Peritectic reaction occurs during the icosahedral quasicrystal formation which leads to element content difference in primary stage and in final stage of icosahedral quasicrystal evolution.The composition analyses show that Mg content is lower but Zn and Y contents are higher in the primary stage of quasicrystal growth.

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萬(wàn)迪慶 楊根倉(cāng) 朱滿 周堯和. Mg-Zn-Y三元合金中二十面體準(zhǔn)晶相生長(zhǎng)形貌及其演化[J].稀有金屬材料與工程,2006,35(9):1404~1407.[Wan Diqing, Yang Gencang, Zhu Man, Zhou Yaohe. Growth Morphology and Evolution of Icosahedrai Quasicrystai in Mg-Zn-Y Ternary Alloys[J]. Rare Metal Materials and Engineering,2006,35(9):1404~1407.]
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  • 收稿日期:2005-06-23
  • 最后修改日期:2005-06-23
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