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5V鋰離子電池尖晶石正極材料LiM0.5Mn1.5O4的研究評述
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TM912.9

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Review of Research on Spinel Cathode Materials LiM0.5Mn1.5O4 for 5 V Lithium Ion Battery
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    摘要:

    評述了鋰離子電池錳酸鋰正極材料的重要性，介紹了3d．過渡金屬離子（Cr^3＋，Ni^2＋，Cu^2＋，F(xiàn)e^3＋）摻雜在錳酸鋰正極材料中的應(yīng)用。研究了3d-過渡金屬離子摻雜對錳酸鋰正極材料結(jié)構(gòu)和電化學(xué)性能的影響，并提出了其影響鋰離子電池充放電和循環(huán)性能的機(jī)制。展望了3d-過渡金屬離子摻雜在鋰離子電池錳酸鋰正極材料中的發(fā)展前景，并指出LiM0.5Mn1.5O4是非常有應(yīng)用前景的5V鋰離子電池正極材料。

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    The importance of developing positive materials of lithium manganese oxide for lithium ion battery is expounded, and the applications of 3d transition metal ions (Cr3+, Ni2+, Cu2+, Fe3+) doped in positive materials of lithium manganese oxide are introduced. Effects of 3d transition metal ion doped on structure and electrochemical performance of positive materials of lithium manganese oxide are studied, and the mechanism of influences on the cycle and charge-discharge performance of lithium ion battery is proposed. The development foreground of 3d transition metal ions doped in positive materials of lithium manganese oxide is viewed. It is suggested that the LiNi0.5Mn1.5O4 has the promising application foreground for positive materials of 5 V lithium ion battery.

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伊廷鋒 胡信國 霍慧彬 高昆.5V鋰離子電池尖晶石正極材料LiM0.5Mn1.5O4的研究評述[J].稀有金屬材料與工程,2006,35(9):1350~1353.[Yi Tingfeng, Hu Xinguo, Huo Huibin, Gao Kun. Review of Research on Spinel Cathode Materials LiM0.5Mn1.5O4 for 5 V Lithium Ion Battery[J]. Rare Metal Materials and Engineering,2006,35(9):1350~1353.]
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  • 收稿日期:2005-09-01
  • 最后修改日期:2005-09-01
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