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燒結(jié)氣氛對Ti(CN)基金屬陶瓷飽和磁化強(qiáng)度的影響
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TQ174.758

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國家“863”(B類)項目(2002AA331091);湖南省科技廳重點科研攻關(guān)項目(04GK2010)


Influence of Sintering Atmosphere on the Saturation Intensity of the Ti(CN)Base Ceramets
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    摘要:

    用X射線衍射、電子背散射像、鈷磁儀和矯頑磁力計分析研究了燒結(jié)氣氛(真空,N2,Ar)對Ti(C,N)基金屬陶瓷合金的化學(xué)成分、飽和磁化強(qiáng)度和矯頑磁力的影響。結(jié)果表明:金屬陶瓷混合料壓坯在Ar氣、真空、N2氣等3種不同的氣氛中燒結(jié)后,相應(yīng)合金的碳、氮、氧總量依次增加,相應(yīng)合金中粘結(jié)相的晶格常數(shù)依次減小,飽和磁化強(qiáng)度依次增大。Ar氣和N2氣燒結(jié)造成金屬陶瓷合金的組織結(jié)構(gòu)不均勻,N2氣燒結(jié)影響更大,矯頑磁力出現(xiàn)異常。鈷磁和矯頑磁力可以作為金屬陶瓷合金化學(xué)成分和組織結(jié)構(gòu)變化的一個判據(jù)。

    Abstract:

    The effects of sintering atmospheres(vacuum,N2,Ar)on the chemical composition,saturation intensity and coercive force were studied by using X-ray diffraction,electrons back scattered images,Co-% magnetism meter and coercive force meter for the Ti(CN)base ceramets.The test results indicated that the total amount of the C,N,O and the saturation intensity were increased,but the lattice constant of binder phase was decreased in the corresponding alloy after the green compacts of Ti(CN)base ceramets were sintered in Ar,vacuum,N2,respectively.It caused a non-uniform construction if sintering in Ar and N2;even more influence in N2,resulting in a disorder coercive force.The values of Co-% magnetism and coercive force could be used as a criterion of the change of chemical composition and structure.

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周書助 王社權(quán) 王零森 胡茂中.燒結(jié)氣氛對Ti(CN)基金屬陶瓷飽和磁化強(qiáng)度的影響[J].稀有金屬材料與工程,2006,35(8):1299~1302.[Zhou Shuzhu, Wang Shequan, Wang Lingsen, Hu Maozhong. Influence of Sintering Atmosphere on the Saturation Intensity of the Ti(CN)Base Ceramets[J]. Rare Metal Materials and Engineering,2006,35(8):1299~1302.]
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  • 收稿日期:2005-06-20
  • 最后修改日期:2005-10-09
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