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鈦在H2O2溶液中的腐蝕特性研究
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TG146.23

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Corrosion Behavior of Titanium in Hydrogen Peroxide Solutions
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    摘要:

    通過分光光度計測定腐蝕后溶液中鈦離子濃度的方法,研究了鈦在H2O2溶液中的腐蝕特性,以及不同pH值條件下,K^+,Ca^2+,Na^+,Mg^2+,Cl^-,HPO4^2-,H2PO4^-等添加離子對鈦腐蝕的影響。結果表明:Ca^2+對鈦腐蝕具有最強的抑制性,而HPO4^2-則具有最強的促進作用。分析認為:Ca^2+通過吸附到鈦表面形成CaTiO3或者CaO2來抑制鈦的腐蝕:而HPO4^2-則是吸附到鈦表面來增加表面氧化膜的缺陷,從而促進鈦的腐蝕。

    Abstract:

    The corrosion behavior of titanium in hydrogen peroxide solutions was studied by measuring the titanium ions concentration using spectrophotometer.The influence of additives(K+,Ca2+,Na+,Mg2+,Cl-,HPO42-,H2PO4-)on the corrosion behavior of titanium was discussed under different pH conditions.The results indicated that Ca2+ exhibited the highest inhibition to the titanium corrosion in hydrogen peroxide solutions.However,HPO42-behaved as an accelerator to the corrosion.It was considered that the Ca2+ inhibited the titanium corrosion probably by absorbed on the titanium surface to form a thin film of CaTiO3 or CaO2.The HPO42-accelerated the titanium corrosion,however,probably by increasing the defects of surface oxide films after absorption on the titanium surface.

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謝雷 王小祥.鈦在H2O2溶液中的腐蝕特性研究[J].稀有金屬材料與工程,2006,35(8):1219~1222.[Xie Lei, Wang Xiaoxiang. Corrosion Behavior of Titanium in Hydrogen Peroxide Solutions[J]. Rare Metal Materials and Engineering,2006,35(8):1219~1222.]
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  • 收稿日期:2005-05-23
  • 最后修改日期:2005-09-28
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