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濕度對(duì)納米鋁粉活性影響的研究
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TB44

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國(guó)家自然科學(xué)基金(50471061)


Effects of Humidity on Activity of Aluminum Nanoparticles
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    摘要:

    研究了存儲(chǔ)環(huán)境濕度對(duì)納米鋁粉活性的影響,并對(duì)其變化機(jī)理進(jìn)行了較深入的探討.結(jié)果表明,環(huán)境濕度對(duì)納米鋁粉的活性影響十分明顯:在相同存儲(chǔ)時(shí)間內(nèi),隨著環(huán)境濕度的增加,納米鋁粉的熱焓和活性鋁含量顯著減少;原始納米鋁粉是被一層3 nm厚非晶態(tài)氧化鋁包覆的殼層結(jié)構(gòu),在不同濕度條件下放置8周后,殼層厚度將逐漸增加至5 nm,隨后不再繼續(xù)增加.但在高濕度條件下,納米鋁粉顆粒芯部發(fā)現(xiàn)了類(lèi)似殼層的非晶態(tài)結(jié)構(gòu),表明氧化行為仍在通過(guò)其它途徑進(jìn)入到了納米鋁粉的芯部.同時(shí),在對(duì)納米鋁粉DSC-TG分析中還發(fā)現(xiàn)存在兩次氧化現(xiàn)象.

    Abstract:

    A qualitative study on the effects of humidity on activity of aluminum nanoparticles has been reported in this letter. The Al nanoparticles were synthesized by the process of hybrid induction and laser heating (HILH). In order to understand the stability of the oxide coating from aluminum nanoparticles, the Al nanoparticles were examined using high-resolution transmission electron microscopy (HRTEM) and the thermal behaviors were identified by DSC-TG. It was found that a compact amorphous oxide layer of 3 nm in thickness covered the original Al nanoparticles. After stored for 8 weeks, the oxide layer grew up to 5 nm in thickness, and the oxidation diffused to the interior of Al nanoparticles. The results indicate that the activity of Al nanoparticles is deeply influenced by the environment, especial the humidity. A higher relative humidity would accelerate the aging of Al nanoparticles. The DSC-TG results show that the oxidation of Al nanoparticles occurs at least in two steps.

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李穎 宋武林 謝長(zhǎng)生 曾大文 胡木林 王愛(ài)華.濕度對(duì)納米鋁粉活性影響的研究[J].稀有金屬材料與工程,2006,35(7):1150~1153.[Li Ying, Song Wulin, Xie Changsheng, Zeng Dawen, Hu Mulin, Wang Aihua. Effects of Humidity on Activity of Aluminum Nanoparticles[J]. Rare Metal Materials and Engineering,2006,35(7):1150~1153.]
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  • 收稿日期:2005-04-18
  • 最后修改日期:2006-03-14
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