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Eu~(3+)摻雜ZnO-MgO-La_2O_3-B_2O_3基發(fā)光光纖的彈脆塑性
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TN818;

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國家自然科學(xué)基金資助項目(20261006),吉林省科技發(fā)展計劃項目(20040506-2)


Elastic-Brittle-Plasticity of Luminescence Fibers of Eu~(3+) Doped ZnO-MgO- La_2O_3-B_2O_3
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    摘要:

    采用高溫固相反應(yīng)法制備了Eu3+摻雜ZnO-MgO-La2O3-B2O3基質(zhì)的光致發(fā)光光纖,通過軸向拉伸試驗測量了該光纖的應(yīng)力-應(yīng)變曲線。應(yīng)用彈脆塑性理論研究了屈服面的變化和應(yīng)力-應(yīng)變的本構(gòu)關(guān)系,計算了拉伸彈性模量、拉伸強度、拉伸最大負荷、拉伸強度的應(yīng)變、斷裂伸長率和材料的脆性指數(shù)。結(jié)果表明,該光纖彈性模量高于普通玻璃和大理石,接近于硬鋁合金和軋制鋁,其拉伸強度和所能承載的負荷都較大。

    Abstract:

    Luminescence fibers of Eu3+ doped ZnO-MgO-La2O3-B2O3 were prepared by solid state reaction at high temperatures. Their diameters were in the range of 0.01 mm~0.30 mm and their lengths were more than 10 m. Their curves of stress-strain were measured by the axial extension test. The change of the yield surface and the constitutive relations of the stress-strain were investigated based on the theory of elastic-brittle-plastic. Their elastic modulus, intensity, stress peak load, strain of stress intensity, elongation ratio to rupture of the axial extension, and brittleness index of the material were calculated. It is found that their strong emission band of Eu3+ with a maximum at 614 nm belongs to the electric dipole transition of 5D0-7F2 and the emission at 581 nm with 40% relative intensity to 614 nm belongs to magnetic dipole transition of 5D0-7F1. The host emission peak presenting to 438 nm overlaps its excitation band. The result shows that their elastic modulus are higher than those of common glass and marble, close to hard aluminum alloy and rolled aluminum. Their stress intensity and peak load are relatively big.

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郭振平,常樹嵐,林沛和. Eu~(3+)摻雜ZnO-MgO-La_2O_3-B_2O_3基發(fā)光光纖的彈脆塑性[J].稀有金屬材料與工程,2005,34(9).[Guo Zhenping, Chang Shulan, Lin Peihe. Elastic-Brittle-Plasticity of Luminescence Fibers of Eu~(3+) Doped ZnO-MgO- La_2O_3-B_2O_3[J]. Rare Metal Materials and Engineering,2005,34(9).]
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