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熱處理對碳/碳復(fù)合材料上堿液處理氧化鈦鍍層誘導(dǎo)沉積磷灰石和結(jié)合強(qiáng)度的影響
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R318.08

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國家自然科學(xué)基金(50002008) 西安交通大學(xué)博士論文基金(2000-02)資助


Effect of Heat Treatment on Induced Apatite Deposition and Bonding Strength of the Alkali Treated Titanium Oxide Layer for Carbon/Carbon Composite
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    摘要:

    碳/碳復(fù)合材料具有良好的力學(xué)性能和生物相容性,料上制備了氧化鈦膜層,并進(jìn)行了堿液處理、真空熱處理、但沒有生物活性。采用離子束增強(qiáng)沉積技術(shù)在碳/碳復(fù)合材模擬體液浸泡和劃痕試驗(yàn)。研究發(fā)現(xiàn)氧化鈦膜層經(jīng)過堿液處理形成的多孔網(wǎng)狀鈦酸鈉凝膠層,可在模擬體液中誘導(dǎo)沉積出牛物活性磷灰石層。鈦酸鈉凝膠層經(jīng)過熱處理變得致密,誘導(dǎo)沉積磷灰石層的速度有所下降。劃痕試驗(yàn)表明堿液處理氧化鈦鍍層的結(jié)合強(qiáng)度在熱處理后略有提高,但膜層的結(jié)合性能受到碳/碳復(fù)合材料較軟的限制。

    Abstract:

    Carbon/carbon composite has good mechanical properties and biocompatibility, but has no bioactivity. Titanium oxide film was deposited onto the carbon-carbon composite using ion beam enhanced deposition, then subjected to alkali treatment, heat treatment in vacuum, immersion in the simulated body fluid (SBF) and scratch test. It was found that a porous network of sodium titanate gel was formed after the titanium oxide film was alkali treated, and the gel layer could induce deposition of bioactive apatite layer in SBF. The porous gel layer became denser and the apatite deposition rate was decreased after heat treatment. The scratch test showed that the bonding strength of the alkali treated titanium oxide film was slightly increased after heat treatment, but bonding strength of the films was limited by the soft carbon/carbon composite substrate.

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付濤 憨勇 徐可為.熱處理對碳/碳復(fù)合材料上堿液處理氧化鈦鍍層誘導(dǎo)沉積磷灰石和結(jié)合強(qiáng)度的影響[J].稀有金屬材料與工程,2005,34(6):946~949.[Fu Tao, Han Yong, Xu Kewei. Effect of Heat Treatment on Induced Apatite Deposition and Bonding Strength of the Alkali Treated Titanium Oxide Layer for Carbon/Carbon Composite[J]. Rare Metal Materials and Engineering,2005,34(6):946~949.]
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  • 最后修改日期:2003-11-07
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