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熱力因素對合金元素在Ti-24Al-15Nb-1.5Mo/TC4焊接界面上擴(kuò)散規(guī)律的影響
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TG142.71 X16

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Effect of Hot and Force Factors on the Microhardness and Elements Diffusion at Ti_3Al/TC 4 Seam
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    摘要:

    研究了2種狀態(tài)的金屬間化合物基合金Ti-24Al-15Nb-1.5Mo與TC4鈦合金毛坯經(jīng)真空電子束焊接后,鍛造溫度、熱處理制度、變形量等熱力因素以及它們的交互作用對合金元素Al,Nb,V在焊接界面上擴(kuò)散規(guī)律的影響。研究發(fā)現(xiàn):增加變形和提高熱處理溫度,可以增大原子遷移的動能,有利于提高合金元素的擴(kuò)散速度,均勻焊縫顯微硬度:加大變形量,有利于提高品格畸變能并細(xì)化晶粒、改變相的形態(tài)、減小相的尺寸,縮短合金元素的擴(kuò)散路程。Nb在重新凝固區(qū)Ti-24Al-15Nb-1.5Mo一側(cè)濃度高于合金的名義成分是由于在焊縫區(qū)α2→α變化時,Nb從DO19結(jié)構(gòu)點陣中擴(kuò)散出來,填補Al,Mo擴(kuò)散后的空位,造成局部堆積所致。變形后熱處理規(guī)范的不同,導(dǎo)致焊縫區(qū)的顯微硬度不同,這與熱處理過程中顯微組織變化有關(guān)。

    Abstract:

    The influence of heat and force factors and their interaction, such as forging temperature, heat treatment process, deformation amount, on the element diffusion of Al, Nb, V at weld zone has been investigated for the Ti-24Al-15Nb-1.5Mo/TC4 dual alloy billet after welded in vacuum and rolled or treated. Investigations showed that the energy of atom motion can increase with the increase of deformation amount and heat treatment temperature, favorable for the elements diffusion and the homogenization of micro-hardness due to the change of shape and size for the grains and phases and short diffusion journey of fine grains at the weld seam. It is found that the concentration of niobium is high at the Ti-24Al-15Nb-1.5Mo side of weld seam. There are two reasons: one is niobium diffusion out from DO19 lattice when re-solidified during welding; the other is local deposit of niobium to fill up the vacancies when AI, Mo diffused out the lattice. The heat treatment route can affect the diffusion rate through changing the morphology of microstructure at weld zone.

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姚澤坤 梁新民 郭鴻鎮(zhèn) 陳紹楷 張會.熱力因素對合金元素在Ti-24Al-15Nb-1.5Mo/TC4焊接界面上擴(kuò)散規(guī)律的影響[J].稀有金屬材料與工程,2005,34(6):907~911.[Yao Zekun, Liang Xinmin, Guo Hongzhen, Chen Shaokai, Zhang Hui. Effect of Hot and Force Factors on the Microhardness and Elements Diffusion at Ti_3Al/TC 4 Seam[J]. Rare Metal Materials and Engineering,2005,34(6):907~911.]
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