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電流密度對鎂合金微弧氧化過程及氧化陶瓷膜性能的影響
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TG174.451

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Effect of Current Density on Mechanism of Micro-Arc Oxidization and Property of Ceramic Coating Formed on Magnesium Alloys
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    摘要:

    在含有硅酸鈉、氟化鈉、甘油的電解液中以恒電流方式對鎂合金進(jìn)行微弧氧化。考察了電流密度對放電電壓、起火時間及陶瓷膜厚度的影響。利用掃描電鏡觀察了在不同電流密度下形成的陶瓷膜的表面形貌;通過電化學(xué)交流阻抗測量了不同電流密度下得到的陶瓷氧化膜的耐蝕性能。結(jié)果表明:在恒電流微弧氧化過程中,依據(jù)電壓.時間曲線,可簡單地分為電壓持續(xù)增長階段和電壓基本穩(wěn)定階段,且隨著電流密度的增加,曲線斜率逐漸增大:電流密度的增大,可以降低起火時間,增加陶瓷氧化膜的厚度,但對放電電壓并沒有明顯的影響:隨著電流密度的增大,陶瓷層表面微孔數(shù)量減少.孔徑增大,呈現(xiàn)出的熔融狀態(tài)更為明顯;陶瓷氧化膜的耐蝕性隨著電流密度的升高呈現(xiàn)先增強(qiáng)后減弱的趨勢。

    Abstract:

    Magnesium alloys were treated in a solution containing silicate, fluoride and glycerol at a constant applied current density. The effect of current density on breakdown voltage, ignition time and coating thickness was investigated. SEM was employed to examine the surface morphology of ceramic coatings formed on magnesium alloys at different applied current density, and the corrosion resistance was also measured by EIS. It was concluded that according to the Voltage-Time response, the MAO process is simply divided into gradually increasing stage and a relative stable stage. With the increase of applied current density the cell voltage increasing rate is improved, coating thickness is increased lineally and ignition time is decreased, but the breakdown voltage has no apparent variation. The number of pores is decreased with the increase of current density, but the diameters of the pores are increased; EIS results indicate that corrosion resistance of ceramic coating increase firstly, then decrease with the increase of applied current density.

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郭洪飛 安茂忠 徐莘 霍慧彬.電流密度對鎂合金微弧氧化過程及氧化陶瓷膜性能的影響[J].稀有金屬材料與工程,2005,34(10):1554~1557.[Guo Hongfei, An Maozhong, Xu Shen, Huo Huibin. Effect of Current Density on Mechanism of Micro-Arc Oxidization and Property of Ceramic Coating Formed on Magnesium Alloys[J]. Rare Metal Materials and Engineering,2005,34(10):1554~1557.]
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  • 收稿日期:2004-06-07
  • 最后修改日期:2005-07-09
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