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部分熔化處理工藝對(duì)(Bi,Pb)-2223/Ag帶材相組成和微結(jié)構(gòu)的影響
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TG146.4

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國(guó)家“973”基礎(chǔ)研究項(xiàng)目“Bi系帶材基礎(chǔ)性研究”(G199906-46-05)


Effect of the Partial Melting Process on the Phase Assemblage and Microstructure of the (Bi,Pb)-2223/Ag Strip
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    摘要:

    通過部分熔化處理工藝和普通兩段熱處理工藝的對(duì)比研究,分析了部分熔化處理工藝在不同熱處理階段對(duì)(Bi,Pb)-2223/Ag帶材相組成和微結(jié)構(gòu)的影響。實(shí)驗(yàn)結(jié)果顯示,在熔化溫度下,部分(Bi,Pb)-2212相發(fā)生分解,分解為(Sr,Ca)2CuO3相、(Sr,Ca)Cu2O3相和富(Bi,Pb)液相,與此同時(shí)(Sr,Ca)2CuO3相和(Sr,Ca)Cu2O3相快速長(zhǎng)大。隨著冷卻和成相處理,(Sr,Ca)2CuO3相和(Sr,Ca)Cu2O3相長(zhǎng)大到一定尺寸,各相系統(tǒng)達(dá)到平衡后,就不再長(zhǎng)大,并和部分液相反應(yīng),重新生成具有良好取向的(Bi,Pb)-2212相。在成相處理階段,(Bi,Pb)-2212相轉(zhuǎn)化為(Bi,Pb)-2223相,同時(shí)生成的(Bi,Pb)-2223相繼承了(Bi,Pb)-2212相的良好取向,使(Bi,Pb)-2223相織構(gòu)得以改善,致密度得到提高,結(jié)果最終帶材的性能得到提高。通過部分熔化處理工藝處理的帶材Ic達(dá)到51A,而普通兩段熱處理工藝處理的帶材Ic為36A,Ic提高了約40%。

    Abstract:

    The effect of different stages of the partial melting process on the phase component and microstructure of (Bi,Pb)-2223/Ag strip was analyzed and compared to the normal two-stage heat treatment process. The results show that some of the (Bi,Pb)-2212 phase melted and decomposed into (Sr,Ca)2CuO3, (Sr,Ca)Cu2O3 and rich (Bi,Pb) liquid phase. At the same time, the (Sr,Ca)2CuO3 and (Sr,Ca)Cu2O3 phases grew rapidly. During cooling and phase formation, the (Sr,Ca)2CuO3 and (Sr,Ca)Cu2O3 phases stop growing when they reach a certain size and react with liquid phase to recreate the (Bi,Pb)-2212 phase with good orientation. At the phase formation stages, the (Bi,Pb)-2223 phase during transformation from the (Bi,Pb)-2212 phase inherits the good orientation of (Bi,Pb)-2212 phase. This results in an improvement in the texture and the density of the (Bi,Pb)-2223 phase which in turn results in an improvement of the critical current. The final strip made by the partial melting process has a critical current of 51 A (while the strip made by the normal two-stage heat treatment process have the lower critical current of 36 A). Thus the new method increases the critical current by about 40%.

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劉育松 張平祥 李成山 于澤銘 鄭會(huì)玲 熊曉梅 劉奉生 姜冰 梁明 馮勇 周廉.部分熔化處理工藝對(duì)(Bi,Pb)-2223/Ag帶材相組成和微結(jié)構(gòu)的影響[J].稀有金屬材料與工程,2004,33(9):984~987.[Liu Yusong, Zhang Pingxing, Li Chengshan, Yu Zeming, Zheng Huiling, Xiong Xiaomei, Liu Fengsheng, Jiang Bing, Liang Ming, Feng Yong, Zhou Lian. Effect of the Partial Melting Process on the Phase Assemblage and Microstructure of the (Bi, Pb)-2223/Ag Strip[J]. Rare Metal Materials and Engineering,2004,33(9):984~987.]
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