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碳納米管承載氧化鋯納米粒子的研究
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An Investigation of Zirconium Oxide Particles Supported on Carbon Nanotubes
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    摘要:

    在液相沉淀法制備超細粉的工藝中引入碳納米管,作為ZrO2的承載體。TEM觀察發(fā)現添加表面活性劑可以實現碳納米管對ZrO2的有效承載,未加表面活性劑出現了兩者的分離。液相中Zeta電位分布的變化表明表面活性劑的添加有利于碳納米管在水相中的分散,對工藝機理的研究揭示了表面活性劑其疏水基吸附在碳納米管表面,而其親水基與ZrO2水合物結合,在碳納米管承載氧化鋯納米粒子復合材料制備中起到了橋接作用。

    Abstract:

    s: ZrO2 nanoparticles supported on CNTs were prepared by adding CNTs in liquid-disposition process. The TEM photo showed that CNTs and ZrO2 nanoparticles would be separated from each other without the surfactant and be connected well when the surfactant was absorbed on the surface of CNTs. The zeta potential of the CNTs in the solution revealed that the surfactant could help them weltering the aquatic phase and enhance the stability of their dispersion. The surfactant had also functioned as bridges, which hydrophilic groups were jointed with the ZrO2 nanoparticles, and which hydrophobic chains were adhered to the surface of the carbon nanotubes, so the ZrO2 nanoparticles were supported on the surface of the carbon nanotubes through the surfactant.

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羅天勇 李辰砂 梁彤祥 唐春和.碳納米管承載氧化鋯納米粒子的研究[J].稀有金屬材料與工程,2004,33(8):885~888.[Luo Tianyong, Li Chensha, Liang Tongxiang, Tang Chunhe. An Investigation of Zirconium Oxide Particles Supported on Carbon Nanotubes[J]. Rare Metal Materials and Engineering,2004,33(8):885~888.]
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  • 最后修改日期:2002-12-24
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