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合金成分對(duì)鋯合金焊接區(qū)腐蝕時(shí)吸氫性能的影響
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TG146.4

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國(guó)家自然科學(xué)基金資助項(xiàng)目(50171039),中國(guó)核動(dòng)力研究設(shè)計(jì)院核燃料,材料國(guó)家級(jí)重點(diǎn)實(shí)驗(yàn)室基金資助 (514810301.01.QT06.01)


The Effect of Alloying Composition on Hydrogen Uptake of Welding Zones of Zirconium Alloys during Corrosion Tests
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    摘要:

    采用Fe含量相同,但Cr含量不同的鋯合金板與Zr-4板對(duì)接焊,腐蝕后不同樣品中的氫含量差別很在,與氧化膜的厚度不成比例,說(shuō)明合金元素Cr對(duì)鋯合金的吸氫性能有著非常明顯的影響,當(dāng)不含Cr時(shí),焊接樣品腐蝕后的氫含量明顯減少:Zr.4經(jīng)不同熱處理后Zr(Fe,Cr)2第二相的大小和多少與氫含量有關(guān),說(shuō)明合金中存在Cr時(shí)形成的Zr(Fe,Cr)2第二相是引起吸氫量增加的主要原因。在不含Cr的鋯合金中添加合金元素Nb,不僅改善了焊接區(qū)的耐腐蝕性能,而且不會(huì)引起腐蝕時(shí)吸氫增加。氯化鋯會(huì)在對(duì)接焊樣品中未焊透的前端析出,這是張應(yīng)力引起氫的擴(kuò)散富集并誘發(fā)氫化物析出的結(jié)果。氫化鋯還會(huì)沿著熔區(qū)邊界集中析出,這將影響鋯合金力學(xué)性能的均勻性。

    Abstract:

    When the zirconium alloy plates with the same Fe content and different Cr content were used to make the butt joints with Zr-4 alloy plates, the hydrogen content in welding samples is obviously different after corrosion and is not in proportion to the thickness of oxide films. This shows that alloying element Cr has a significant effect on hydrogen uptake performance. The hydrogen content in welding samples, in which zirconium alloy plates being used to make the butt joints with Zr-4 plates dont contain Cr, decreases sharply after corrosion. The relationship between hydrogen content and the number and size of Zr(Fe,Cr)2 second phase particles in Zr-4 with different heat-treated states indicates that the formation of Zr(Fe,Cr)2 second phase particles is the main reason that the amount of hydrogen uptake increases. Adding Nb alloying element in zirconium alloys without Cr, not only improves the corrosion resistance, but also make hydrogen uptake not to increase. The zirconium hydrides induced by tensile stress are easy to precipitate in the front of faulty fusion, and they are also easy to precipitate along the interface between molten zones and matrix. These will influence the dispersity of mechanical properties.

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姚美意 周邦新 李強(qiáng) 劉文慶 苗志 俞應(yīng)華.合金成分對(duì)鋯合金焊接區(qū)腐蝕時(shí)吸氫性能的影響[J].稀有金屬材料與工程,2004,33(6):641~645.[Yao Meiyi, Zhou Bangxin, Li Qiang, Liu Wenqing, Miao Zhi, Yu Yinghua. The Effect of Alloying Composition on Hydrogen Uptake of Welding Zones of Zirconium Alloys during Corrosion Tests[J]. Rare Metal Materials and Engineering,2004,33(6):641~645.]
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  • 最后修改日期:2002-11-08
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