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元素及其化合物對鎢基高密度合金性能的影響
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TG146.411

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國家“863”計劃資助項目(2002AA305503)


Effects of Elements and Their Compounds on Properties of High Density Alloy
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    摘要:

    詳細分析了鈷、鉬、錳、鉻、錫等主要合金元素及鋁、鈦、鈰等微量元素在鎢基高密度合金中的分布狀況及其化合物對合金性能的影響。合金元素在合金中的作用表現為細化晶粒;強化粘結相:強化鎢晶粒;改善粘結相與鎢顆粒的濕潤性,提高界面結合力;改變雜質元素的存在形式與分布狀態(tài)。綜述了磷、氮、氫、氧、硫和碳等雜質元素在合金相中的存在狀況及其化合物在相界面上的分布特點。磷主要以單質或化合物的形式偏析于界面,增加合金的脆性,但其也能提高燒結的活化性能。氫也會導致脆性;氧通常會降低鎢晶粒與粘結相界面的結合強度;少量的碳可降低磷的偏析,碳含量增加時,會使合金的動態(tài)拉伸強度下降。

    Abstract:

    The distribution of major elements Co, Mo, Mn, Gr etc and trace elements Al, Ti, Ce, La etc and the effects of their compounds on properties of high density alloy were analyzed respectively. The effects of elements in alloy are refining grains, strengthening binder, strengthening tungsten grains, increasing the interface bonding, improving wetting power between binder and tungsten grains and affecting the distribution and morphology of impurities. The distribution characteristics of impurities and their compounds on boundaries were reviewed. Phorsphor which segregates on the boundaries with free state or compounds results in the fragility of the alloy and increasing the sintering activation ability. Hydrogen will also results in fragility by decrease the bonding strength of interface. Minor carbon will decrease the segregation of P, but with increasing carbon content, the dynamic tensile strength of alloy will decrease.

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黃勁松 周繼承 黃伯云.元素及其化合物對鎢基高密度合金性能的影響[J].稀有金屬材料與工程,2004,33(5):454~458.[Huang Jinsong, Zhou Jicheng, Huang Baiyun. Effects of Elements and Their Compounds on Properties of High Density Alloy[J]. Rare Metal Materials and Engineering,2004,33(5):454~458.]
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  • 最后修改日期:2002-10-15
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