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液相滲入-反應法制備木材結構SiC的研究
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TB383

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國家自然科學基金資助項目(50272051)


Preparation of Biomorphic SiC-Ceramics by the Reactive Infiltraion of Si into Carbon Template Derived from Basswood
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    摘要:

    椴木經(jīng)高溫炭化轉變?yōu)槟咎?,?jīng)熔融硅反應性滲入后,生成具有椴木微觀結構的多孔SiC陶瓷。借助TGA(采用Rigaku Thermal型熱分析儀)研究了椴木的熱分解行為,用XRD和SEM研究了椴木木炭和多孔SiC陶瓷的物相組成和微觀結構,還探討了Si向木炭中滲入.反應動力學和多孔SiC的基本性能。結果顯示,木炭為無定形的非晶碳材料,多孔SiC由主晶相β-SiC和少量未反應C組成的;多孔SiC具有椴木的管胞結構,與木炭相比,力學性能得到顯著改善;碳纖維向SiC纖維的轉化及其對裂紋萌生、擴展的抑制作用和偏轉作用是提高力學性能的主要機制。

    Abstract:

    Basswood was transformed by high-temperature pyrolysis into carbon performs (charcoal) and subsequently converted into cellular SiC-ceramics possessing pseudomorphous microstructure by the reactive-infiltration of Si into CB-template in Ar atmos- phere.Thermogravimetric analysis (TGA) was applied to reveal the pyrolysis behavior of basswood powder.Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were employed to characterize and analyze the microstructures and phase identification of CB-template and final SiC ceramics.The infiltration mechanism of liquid Si into charcoal and the basic properties of cellular SiC were also given.The results showed that CB-template was amorphous carbon materials.Final cellular SiC was composed of the major phase ?-SiC and a little unreacted carbon.Compared to charcoal,cellular SiC possessed higher mechanical properties.The improvement of the mechanical properties of materials was mainly caused by the following factors:one was the conversion of carbon fibres into SiC fibres,and the another was the volume expansion during CB-template-to-cellular SiC conversion,which inhibited the initiation and propagation of cracks and made cracks deflect.

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錢軍民 王繼平 金志浩.液相滲入-反應法制備木材結構SiC的研究[J].稀有金屬材料與工程,2004,33(10):1065~1068.[Qian Junmin, Wang Jiping, Jin Zhihao. Preparation of Biomorphic SiC-Ceramics by the Reactive Infiltraion of Si into Carbon Template Derived from Basswood[J]. Rare Metal Materials and Engineering,2004,33(10):1065~1068.]
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  • 最后修改日期:2003-02-25
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