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固溶電場對鋁鋰合金析出動力學(xué)的影響
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TG113.5

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國家自然科學(xué)基金(59871039)


Effects of Electric Field Applied during Solution Treatment on Precipitation Kinetics in an Al-Li Alloy
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    摘要:

    采用差熱掃描(DSC)分析,研究了在2090鋁鋰合金固溶過程中施加的電場對合金析出動力學(xué)的影響,并探討了電場作用的微觀機理。研究發(fā)現(xiàn),固溶電場使δ′相和T1相析出的峰值溫度略有降低,使析出曲線提前,并使T1相的析出焓變有所減小,而對δ′相的析出焓變基本無影響;同時,固溶電場增大δ′相和T1相的前期析出速率,但減小它們的后期析出速率;固溶電場還降低了δ′相和T1相的析出激活能。作者認(rèn)為,固溶電場通過對合金中空位的作用,提高了空位的濃度及合金元素的固溶程度,從而降低這兩相的析出激活能。

    Abstract:

    The effects of an electric field appl ied du ring solution treatment on the precipitation kinetics in Al-Li all oy 2090h ave been studied using differential scanning calorimetry(DSC).It is found tha t electric field decreases the peak temperatures of?' and T 1 phases precipitation,bringing their curves forward.It le ssens the enthalp y of T 1 precipitation,while keeping that of?' precipitation unchanged.At the sa m e time,the electric field increases the rates of?' and T 1 precipitation in the first stages,while decreases those in the last stages .An electric field also reduces the activation energies of?' and T 1 phases precipitations.It is though t that the electric field increases t he concentration of vacancies and the hence solubility of alloying elements,there by decreasing the activation energies of these two precipitation mechanisms.

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魏齊龍 陳錚 劉兵.固溶電場對鋁鋰合金析出動力學(xué)的影響[J].稀有金屬材料與工程,2003,(9):723~726.[Wei Qilong, Chen Zheng, Liu Bing. Effects of Electric Field Applied during Solution Treatment on Precipitation Kinetics in an Al-Li Alloy[J]. Rare Metal Materials and Engineering,2003,(9):723~726.]
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  • 最后修改日期:2002-03-04
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