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氧化物—空氣半燃料電池用貯氫合金電極的燒結(jié)制備及其電化學(xué)特性
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TM911.4

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教育部回國基金,湖北省自然科學(xué)基金和華中科技大學(xué)基金資助項(xiàng)目


Electrochemical Characteristics and Sintering Preparation of Metal Hydride Electrode for Air MH Semi fuel Cell Applications
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    摘要:

    研究了應(yīng)用在空氣-氫化物半燃料電池上的制備配套金屬氫化物厚型電極燒結(jié)技術(shù),將貯氫合金與細(xì)鎳粉和一定的添加劑形成漿料涂覆在泡沫鎳基體,測試不同燒結(jié)參數(shù)對貯氫合金電極的電化學(xué)性能的影響,燒結(jié)電極合金的電化學(xué)活化特性和高倍率放電能力與傳統(tǒng)的粘結(jié)式電極有較大的提高,為設(shè)計(jì)適合電動(dòng)車用高能量密度空氣-氫化物燃料電池,分別選用沖孔鎳箔帶,沖孔銅箔帶和銅編織網(wǎng)作為集流體進(jìn)行比較實(shí)驗(yàn)。結(jié)果表明,選定沖孔銅箔帶是適宜于設(shè)計(jì)空氣-氫化物燃料電池用厚型氫化物電極。

    Abstract:

    The powder sintered technology for manufacturing thick metal hydride electrodes has been extensively investigated. A slurry consisting of hydrogen storage alloy powder mixed with fine nickel powder and some additives was pasted onto the nickel foam as a current collector. By choosing adjustable sintering parameters, the composite metal hydride electrode was obtained. The effects of sintering parameters on the electrochemical properties of sintered metal hydride electrode have been characterized. The results showed that the activation and high rate discharge ability were greatly improved and comparable to that obtained with conventional pasting process for sintered hydride electrode. In order to design the thick metal hydride electrode Suitable for the oxygen diffusion electrode of airmetal hydride semi fuel cell, the electrochemical characteristics of thick metal hydride electrode were comparativly studied for different metal substrates, suchas perforated nickel strip, perforated copper foil and copper mesh. As a consequence, the thick metal hydride electrode employing the perforated copper foil as a current collector has been evaluated to be suitable for the airmetal Hydride semi fuel cell.

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江建軍.氧化物—空氣半燃料電池用貯氫合金電極的燒結(jié)制備及其電化學(xué)特性[J].稀有金屬材料與工程,2003,(3):201~204.[Jiang Jianjun. Electrochemical Characteristics and Sintering Preparation of Metal Hydride Electrode for Air MH Semi fuel Cell Applications[J]. Rare Metal Materials and Engineering,2003,(3):201~204.]
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  • 最后修改日期:2001-06-18
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