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Ti—13Al—29Nb—2.5Mo合金ISM熔煉過程中多組元揮發(fā)損失
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TF133

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國家973資助項目(G2000067202-2)


Evaporation Loss of the Components in Ti-13Al-29Nb-2.5Mo Melt during ISM Process
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    摘要:

    在基于活度系數(shù)計算模型的基礎(chǔ)上,計算了ISM熔煉過程中不同熔煉溫度下Ti-13Al-29Nb-2.5Mo(ω/%)熔體中Ti,Al,Nb元素的飽和蒸氣壓,計算結(jié)果表明,在熔煉溫度范圍內(nèi),Al元素的飽和蒸氣壓分別比Ti,Nb元素的飽和蒸氣壓大17倍和3070倍左右。在熔煉溫度范圍內(nèi)對熔體中Al,Ti,Nb元素的揮發(fā)損失速率的計算表明,Al元素在損失速率比Ti,Nb的損失速率分別大43倍和144倍左右,在此基礎(chǔ)上計算了Ti,Al,Nb元素的揮發(fā)損失量以及合金在熔煉后的化學(xué)成分,結(jié)果表明由于合金中各組元的揮發(fā)損失速率大小不一,使得熔煉前后合金的成分出現(xiàn)了變化。分析表明合理降低熔煉溫度及增加真空室中壓力可以減小成分的變化。本結(jié)果為ISM熔煉實踐中合金成分控制提供有價值的理論指導(dǎo)。

    Abstract:

    Based on the activity coefficient calculation module, the saturated pressures of Ti, Al and Nb elements in molten Ti-13Al-29Nb-2.5Mo (mass fraction) at different melting temperatures were calculated. The saturated pressure of element Al in the melting temperature is as big as 17 and 3 070 times of those of Ti and Nb elements respectively. The mass loss rates of Al, Ti, Nb in the melt during the process were also calculated. The mass loss rate of Al is as big as 43 and 144 times of those of Ti, Nb. Based on the evaporation loss rate, the evaporation loss quantity of the elements and the alloy chemical composition after the ISM process was also calculated. Because the mass loss rates of Al, Ti and Nb are different, the ultimate alloy chemical composition deviated from its original composition after the melting process. Analysis shows that properly decreasing the melting temperature and/or increasing the chamber pressure can decrease the composition deviation. This article will give some valuable guidance to the alloy composition controlling during ISM process.

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劉貴仲 蘇彥慶 等. Ti—13Al—29Nb—2.5Mo合金ISM熔煉過程中多組元揮發(fā)損失[J].稀有金屬材料與工程,2003,(2):108~112.[Liu Guizhong, Su Yanqing, Guo Jingjie, Ding Hongsheng, Jia Jun, Fu Hengzhi. Evaporation Loss of the Components in Ti-13Al-29Nb-2.5Mo Melt during ISM Process[J]. Rare Metal Materials and Engineering,2003,(2):108~112.]
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  • 最后修改日期:2001-06-18
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