Al-substituted a-Ni(OH)2 was synthesized by chemical co-precipitation and its structure and thermal stability were studied through XRD, IR, SEM and TGA. The electrochemical properties were studied by cyclic voltammetric method. The results show that the 25mol% Al-substituted Ni(OH)2 is a-Ni(OH)2 and stable in alkali solution. Compared with )3-Ni(OH)2, the proton diffusion coefficient for a-Ni (OH)2 prepared in this paper is higher and the electrode reaction is controlled by the diffusion.
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張倩 徐艷輝 王曉琳. Al代α-Ni(OH)2的結(jié)構(gòu)與電化學(xué)性能[J].稀有金屬材料與工程,2003,(10):825~828.[Zhang Qian, Xu Yanhui, Wang Xiaolin.[J]. Rare Metal Materials and Engineering,2003,(10):825~828.] DOI:[doi]