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表面活性劑對(duì)金屬粉末注射成形喂料性能的影響
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TF124.39

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“863”高新技術(shù)計(jì)劃資助項(xiàng)目(715009009)


Influence of Surfactants on Properties of Metal injection Molding(MIM) Feedstock
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    摘要:

    研究了表面活性劑對(duì)聚乙二醇-聚甲基丙烯酸甲酯/Fe-2Ni粉末注射成形喂料性能的影響。首先用單分子層吸附模型計(jì)算出形成單分子層吸附所需表面活性劑的理論值,然后分別將硬脂酸、司班-20、司班-80、吐溫-60等不同表面活性劑加入粘結(jié)劑中,發(fā)現(xiàn)表面活性劑可通過降低粘結(jié)劑對(duì)粉末的潤濕角、降低粘結(jié)劑-粉末喂料的粘度而提高最大粉末裝載量,在超過單分子層吸附的量之后,繼續(xù)增加表面活性劑、仍能進(jìn)一步發(fā)揮其有益作用。不同表面活性劑對(duì)喂料性能影響的程度有所不同,通過選擇合適的表面活性劑,該聚乙二醇-聚甲基丙烯酸甲酯粘結(jié)劑對(duì)Fe-2Ni羰基粉末裝載量達(dá)55%(體積分?jǐn)?shù))。

    Abstract:

    The effects of various surfactants on properties of the polyethylene glycol (PEG)-Polymethyl methacrylate/Fe-2Ni feedstock are studied. First, one-molecule-layer model is used to calculate theoretically amount of surfactant needed to form onemolecule-layer absorption on powders. Then, different kinds of surfactants , such as, stearic acid, span-20, span-80, tween-60 etc., are added into the binder respectively. It was found that the surfactants increase the maximum powder loading by decreasing contact angle between the binder and the powder, and viscosity of the feedstock. Even the amount of surfactant is much higher than that of one-molecule-layer absorption, the surfactant still have its effective function. The effects of different kinds of surfactants on the properties of feedstock are not the same. By selecting a proper surfactant, the maximum powder loading can reach 55% (volume fraction)for Fe-2Ni carbonyl powder and PEG--based binder.

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李松林 黃伯云 等.表面活性劑對(duì)金屬粉末注射成形喂料性能的影響[J].稀有金屬材料與工程,2001,(2):131~134.[Li Songlin, Huang Baiyun, Qu Xuanhui, Li Yimin. Influence of Surfactants on Properties of Metal injection Molding(MIM) Feedstock[J]. Rare Metal Materials and Engineering,2001,(2):131~134.]
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  • 最后修改日期:2000-03-27
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