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雙粉法制備高性能Bi—2223/Ag多芯帶材
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TM262.051

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HighQuality Bi2223/Ag Multifilament Tapes Fabricated Using a TwoPowder Process
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    摘要:

    采用主相為2212+CaCuO所謂雙粉作為前驅(qū)粉,用標準的粉末套管(PIT)工藝制備了37芯,61芯和85芯BI-2223銀包套多芯帶材,研究發(fā)現(xiàn),采用雙粉裝管縮短了2223成相時間,僅用40h即獲2223純相,前驅(qū)粉中較大尺寸2212片狀晶的存在益于Ca,Cu傳質(zhì)和2223織構(gòu)的提高,通過對加工工藝的精確控制,可有效防止芯絲的不均勻,清除防礙長帶制備的芯絲“香腸”狀現(xiàn)象,首次實現(xiàn)了雙粉法制備高性

    Abstract:

    Many studies have shown that the phase assemblage of starting powders influences the phase evolution of the 2223 phase; but it is quite difficult to control the phase balance in precursor powders using a singlepowder process. In this study, (Bi,Pb)2212 and CaCuO2 are formed as separate intermediate phases, then mixed and processed together within a silver sheath. The phase transformation kinetics, microstructure and transport properties of the resulting tapes are strongly dependence on the phase content of the precursor powders. Nearly pure 2223 can been produced when sintering for as little as 40 h, using (Bi, Pb)2212 and CaCuO2 presursors, and the fraction of nonsuperconducting phases seem to become minimum at the boundary of the oxide core. The effects of mechanical deformation and heat treatment cycles on silvercore interfaces and critical current densities in 37,61 and 85 filament tapes have been studied for the tapes fabricated using the twopowder process. A smooth Agoxide interface has been obtained through accurate control of the pass reduction ratios. This experiment demonstrates that the existence of large platelike 2212 grains in the presursors can accelerate the diffusion of Ca, Cu during sintering stage and increase the degree of texture of 2223 grains.Tapes with a thickness of 024 mm can be made using flat rolling without any sausaging effect. Jc values of 30104 A/cm2(Ic=53 A) and 17104 A/cm2(Ic=35 A) at 77 K and self field are achieved for rolled short samples and tapes 20 m long, respectively.

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李成山 張平祥.雙粉法制備高性能Bi—2223/Ag多芯帶材[J].稀有金屬材料與工程,1999,(3):155~160.[Li Chengshan, Zhang Pingxiang, Wang Ankang, Zheng Huilin, Wu Yifang, Feng Yong, Xi Zhengping, Zhou Lian. HighQuality Bi2223/Ag Multifilament Tapes Fabricated Using a TwoPowder Process[J]. Rare Metal Materials and Engineering,1999,(3):155~160.]
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