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微量Si在W-7Ni-3Fe高比重合金中的行為
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TG146.15

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Investigation on the Behavior of Trace Silicon in W-7Ni-3Fe Heavy Alloy
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    摘要:

    用摻雜微量Si的鎢粉為原料,制備W-7Ni-3Fe高比重合金,用掃描電鏡、X射線光電子能譜儀等研究了微量Si在合金中的行為。結(jié)果表明,原料鎢粉中的微量SiO2在合金中以微粒形式彌散分布在合金的粘結(jié)相中,部分Si以固溶體形式分布在鎢晶粒中;在未摻雜的合金中,發(fā)現(xiàn)有少量的WO2以薄膜形式分布在鎢晶粒的表面,而在摻雜了微量Si的合金試樣中,WO2薄膜消失。探討了摻雜微量Si消除鎢晶粒表面WO2薄膜的機理。

    Abstract:

    -7Ni-3Fe heavy alloy was prepared from the tungsten powders doped with different amounts of trace silicon. The behavior of trace silicon in the tungsten heavy alloy was investigated by using scanning electron microscope GEM) and X-ray photoelectron spectrom etry (XPS). The results showed that part of the trace silicon in the form of dispersed SiO2 particles was distributed in the binder phase of the alloy and the remaining in the state of elemental silicon was distributed in the tungsten grains forming a solid solution. It was found that the tungsten grains in the alloys prepared from undoped tungsten powders were covered by a thin layer of WO2 but no WO2 was detected in the alloys prepareds from doped tungsten powders. The mechanism of the formation and elim mation of WO2 was discussed.

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葛榮德,王盤新,賴和怡.微量Si在W-7Ni-3Fe高比重合金中的行為[J].稀有金屬材料與工程,1994,(5).[Ge Rongde. Investigation on the Behavior of Trace Silicon in W-7Ni-3Fe Heavy Alloy[J]. Rare Metal Materials and Engineering,1994,(5).]
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