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TC4鈦合金微弧氧化膜層高溫氧化性能研究
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1:牡丹江師范學院

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國家自然科學基金面上項目(51672120);; 牡丹江師范學院科研機構(gòu)專項項目(1355JG014)


Study on High Temperature Oxidation Property of TC4 Titanium Alloy by Micro-arc Oxidation
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    摘要:

    利用微弧氧化(MAO)技術在TC4鈦合金表面原位制備陶瓷膜層,并通過硅酸鈉水溶液對膜層進行了封孔處理。采用X射線衍射儀(XRD)分析了膜層相組成,通過掃描電子顯微鏡(SEM)觀察了膜層表面形貌。通過粘結(jié)拉伸測試,比較了膜層在封孔前后與基體的結(jié)合強度。利用高溫氧化實驗,考察了TC4基體及膜層試樣封孔前后的抗高溫氧化性能。結(jié)果表明:微弧氧化膜層與基體間的結(jié)合強度較高,經(jīng)封孔處理及高溫氧化100 h后,膜基結(jié)合強度降低至4.29 MPa。與TC4基體相比,微弧氧化膜層的高溫氧化增重量小,抗高溫氧化性能得到了顯著的提高。封孔處理提高了微弧氧化膜層的致密性,使其能更好地阻止氧透過膜層向基體內(nèi)侵入,進一步提高了膜層的抗高溫氧化性能。

    Abstract:

    Ceramic coatings were prepared in situ on the surface of TC4 titanium alloy by means of micro-arc oxidation(MAO) technology, and the coatings were sealed with sodium silicate aqueous solution. The phase composition of the coatings was analyzed by X-ray diffractometer(XRD), and the surface morphology of the coatings were observed by scanning electron microscope(SEM). Through the bonding tensile test, the bonding strength between MAO coating and substrate before and after sealing was compared. Using high temperature oxidation experiments, the high temperature oxidation resistance of the TC4 substrate and coating samples before and after sealing was investigated. The results show that the bonding strength between MAO coating and substrate is high. After sealing and oxidation at high temperature for 100 h, the bonding strength of the coating decreases to 4.29 MPa. Compared with the TC4 substrate, the high temperature oxidation of the micro-arc oxidation coatings is lower, and the high temperature oxidation resistance is significantly improved. The sealing treatment improves the compactness of the micro-arc oxidation coating, so that it can better prevent oxygen from penetrating the coating into the substrate, and further improve the high temperature oxidation resistance of the coating.

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郝國棟;羅麗妍;蘇爽月;邵長斌;尹龍承;賈相華;郝春麗;. TC4鈦合金微弧氧化膜層高溫氧化性能研究[J].鈦工業(yè)進展,2020,37(6):7-11.

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  • 在線發(fā)布日期: 2021-01-12
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