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純鎂滲鋅處理表面合金化機(jī)制研究
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TF549.9 TG174.445

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A Study on the Mechanism of Surface Zn-alloying for Pure Magnesium
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    摘要:

    對(duì)純鎂進(jìn)行了表面滲鋅處理,研究了擴(kuò)滲溫度及擴(kuò)滲時(shí)間對(duì)于合金化滲層組織、相結(jié)構(gòu)及反應(yīng)層連續(xù)性的影響。結(jié)果表明:擴(kuò)滲溫度的選擇有一個(gè)合適的范圍,溫度過低,擴(kuò)滲速度太慢甚至Zn元素原子的能量達(dá)不到其激活能,不能產(chǎn)生活性原子,擴(kuò)滲過程無法進(jìn)行。溫度過高雖然有利于形成合金化滲層,但會(huì)使基體晶粒粗化,甚至改變整個(gè)基體,而且,溫度過高不利于反應(yīng)層(金屬間化合物區(qū))的穩(wěn)定:擴(kuò)滲時(shí)間的延長會(huì)促使Zn的進(jìn)入量和金屬間化合物的生成量增加,并削弱晶界擴(kuò)散優(yōu)勢的影響,最終使固溶層和反應(yīng)層趨于均勻化。要形成連續(xù)的反應(yīng)層,擴(kuò)滲溫度應(yīng)控制在400℃~420℃,相應(yīng)的擴(kuò)滲時(shí)間為8h以上。

    Abstract:

    Surface Zn-alloying modification was used to treat pure magnesium,and the effect of diffusion temperature and time on the alloyed microstructure,phase structure and the continuity of alloyed layers was studied as well.The results show that there is a reasonable range of the diffusion temperature to form the continual intermetallic compound layer.On the condition that the diffusion temperature is too low,the diffusion rate is also rather slow because there is no activated Zn atoms generated.Conversely,although high diffusion temperature is beneficial for the formation of alloyed layers,the base metal granular may become coarse then,even the whole base may get changed.Furthermore,excessively high temperature is harmful to the stability of the reacted layers(intermetallic compound).The prolongation of diffusion time may accelerate the flow of Zn atoms and therefore the formation of intermetallic compound,and weaken the preponderance of grain boundary,resulting in the uniformity of solution area and reacted area.In order to obtain the continual reacted area,the diffusion temperature has to be controlled within 400 420 and the corresponding diffusion time has to be over 8 h.

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.純鎂滲鋅處理表面合金化機(jī)制研究[J].鈦工業(yè)進(jìn)展,2006,23(3):15-18.

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  • 收稿日期:2005-07-25
  • 最后修改日期:2005-07-25
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